This final report presents and discusses results from a mercury control process development project entitled ''Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems''. This Technical Progress Report presents catalyst activity results from the oxidation catalyst pilot unit at Plant Yates and discusses the status of the pilot unit at Monticello. Two catalyst activity measurement trips were made to Plant Yates during the quarter. During this period, project efforts primarily consisted of operating the catalyst pilot units at the TXU Generation Company LP's Monticello Steam Electric Station and at Georgia Power's Plant Yates. This is the ninth reporting period for the subject Cooperative Agreement. Pilot-scale wet FGD tests are being conducted periodically at each site to confirm the ability to scrub the catalytically oxidized mercury at high efficiency. The pilot-scale tests will continue for approximately 14 months or longer at each of two sites to provide longer-term catalyst life data. The current project is testing previously identified catalyst materials at pilot scale and in a commercial form to provide engineering data for future full-scale designs. Oxidized mercury is removed in the wet FGD absorbers and leaves with the byproducts from the FGD system. The mercury control process under development uses honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone FGD systems. DOE National Energy Technology Laboratory, EPRI, Great River Energy (GRE), TXU Generation Company more » LP, the Southern Company, and Duke Energy.
The project is being co-funded by the U.S. The objective of this project is to demonstrate at pilot scale the use of solid honeycomb catalysts to promote the oxidation of elemental mercury in flue gas from coal combustion, and the use of a wet flue gas desulfurization (FGD) system downstream to remove the oxidized mercury at high efficiency. This document summarizes progress on Cooperative Agreement DE-FC26-04NT41992, ''Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems'', during the time-period January 1 through March 31, 2006. This final report presents and discusses detailed results from all of these efforts, and makes a number of conclusions about what was learned through these efforts. Pilot-scale wet FGD tests were also conducted at a fifth site, but with no catalyst or fixed-structure mercury sorbent upstream. The sites include the two of three sites from this project and two sites where catalytic oxidation pilot testing was conducted as part of a previous DOE-NETL project. Additionally, pilot-scale wet FGD tests have been conducted downstream of mercury oxidation catalysts at a total of four sites. Pilot-scale catalytic oxidation tests have been completed for periods of approximately 14 to19 months at three sites, with an additional round of pilot-scale fixed-structure sorbent tests being conducted at one of those sites. The project has tested candidate materials at pilot scale and in a commercial more » form, to provide engineering data for future full-scale designs. Oxidized mercury not adsorbed is removed in the wet FGD absorbers and leaves with the byproducts from the FGD system. The mercury control process under development uses fixed-structure sorbents and/or catalysts to promote the removal of total mercury and/or oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone FGD systems. DOE National Energy Technology Laboratory (DOE-NETL), EPRI, Great River Energy (GRE), TXU Energy (now called Luminant), Southern Company, Salt River Project (SRP) and Duke Energy. The objective of this project has been to demonstrate at pilot scale the use of solid catalysts and/or fixed-structure mercury sorbents to promote the removal of total mercury and oxidation of elemental mercury in flue gas from coal combustion, followed by wet flue gas desulfurization (FGD) to remove the oxidized mercury at high efficiency.
This document is the final technical report for Cooperative Agreement DE-FC26-04NT41992, 'Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems,' which was conducted over the time-period Januthrough December 31, 2010.
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